Radical substitution: description of the reaction, features, example

In simple words, it is a colorless, odorless gas. It is obtained during oil refining. Since it is extremely fire hazardous, an odorant is added to the technical form. This way you can notice in time that a high concentration of the substance has accumulated in the room. The gas is slightly toxic, but inhalation of vapors negatively affects the human central nervous system. Easily liquefies at high pressure. That is why it is used as fuel. Gas is transported in cylinders or through gas pipelines. The most common form is a mixture of propane and butane.

What is propane-butane

During oil production and refining, these two gases are formed as a by-product. The mixture is liquefied, filled into cylinders and transported for further use.

The propane-butane mixture is sensitive to ambient temperature. Propane is more stable, and butane evaporates at a temperature of 0˚C. To make gas use safe, two seasonal fuel options have been created:

  • summer - ratio 50:50 or 40:60;
  • winter - 70:30 or 90:10.

Propane-butane is used for heating water and heating residential buildings, industrial buildings, and workshops in areas where there is no central gas pipeline or its supply is difficult.

Advantages of liquefied gas:

  • low price and availability;
  • rapid establishment of heating and hot water supply in remote areas;
  • convenient transportation.

Regioselectivity

Starting with propane, secondary carbon atoms appear in the composition of alkane molecules, and with butane, which has two isomers (n-butane and isobutane), tertiary atoms appear, respectively, associated with two and three other carbon atoms. The rate of halogenation varies between atoms and increases in the order “primary → secondary → tertiary.” This phenomenon is called regional directionality of halogenation, or regioselectivity. Quaternary atoms do not participate in radical substitution reactions.

Selectivity depends on the following factors:

  • Reagent activity. The more active the halogen, the weaker the selectivity when replacing hydrogen. Thus, when an alkane reacts with chlorine, regioselectivity is much less than in reactions with bromine, or is not observed.
  • Temperature. Heating leads to a decrease in selectivity.

This is interesting:

General formula of cycloalkanes

Hexane isomers

Chlorination and bromination of propane

In the reaction of propane with chlorine at low temperatures, the selective direction is weakly expressed. Although the radicals produced during the reaction are less energetic and therefore more stable, free chlorine atoms are extremely reactive and attack both secondary and primary atoms, especially at high temperatures.

When heated, chlorine radicals attack primary atoms even more actively, since less energy is spent breaking their bond with hydrogen.

When propane is brominated, regioselectivity due to the lower activity of bromine reaches high values:

Bromination proceeds similarly to the reaction involving the simplest alkanes with a predominant substitution of hydrogen at secondary atoms:

The product of this reaction is 2-bromopropane.

Butane halogenation

In the reactions of butane with chlorine, selectivity does not play a significant role. Even at low temperatures, the ratio of chlorination products can be different:

Bromination of butane shows great selectivity:

The use of propane in the housing and communal services sector

Liquefied gas is used everywhere; it solves many problems in the industrial and domestic spheres. With his help:

  • heat residential buildings and production workshops;
  • carry out gas-flame work, including cutting, welding of metal structures, pipelines, etc.;
  • heat up bitumen when carrying out roofing work;
  • power water heating equipment in houses not connected to centralized systems;
  • indoor air conditioning systems are functioning.

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Stable radicals

Typically, radicals “live” little and are in a hurry to react as quickly as possible. Such radicals exist for seconds or fractions of seconds and are called unstable. But there are those that are stable; their period of existence can reach several years. In inorganic chemistry, stable substances include O3, NO, ClO2, NO2 and others. In the organic section there are more stable radicals. They are divided into several groups:

  • hydrocarbon;
  • hydrazyl;
  • nitroxyl;
  • aminyl;
  • aroxyl;
  • verdazil.

Propane in industry

The technical form of the substance is used:

  • for heating the cabins of heavy-duty vehicles;
  • in welding and cutting of various metal structures;
  • in perfumery, cosmetic production;
  • for the production of varnishes, solvents;
  • in the production of printed products at printing plants - it is used to make copy paper and printing ink;
  • as a flavoring additive;
  • for the production of refrigerant for refrigeration units and air conditioners;
  • in the production and coloring of polymers;
  • for heating workshops, greenhouses, industrial buildings.

Applications of haloalkanes

Chlorinated and brominated alkanes are used as intermediates in various industries, such as the synthesis of high molecular weight compounds, the production of varnishes, paints and solvents. Chloroalkanes serve as raw materials for fluoroalkanes, which cannot be obtained by direct fluorination.

The toxicity of haloalkanes is less, the more active the halogen they contain. Therefore, fluoroalkanes are the safest. Fluorinated freons are widely used as blowing agents, refrigerants and propellants.

LPG for transport

Propane-butane mixture is gaining popularity as an alternative fuel for cars, water transport and aircraft. Its heat of combustion is higher than that of gasoline. Gas prices are approximately half as much, and refueling your car becomes several times more economical.

Propane is a more environmentally friendly fuel; the amount of harmful emissions into the atmosphere (compared to gasoline) is approximately four times lower. The gas mixture does not form carbon deposits on moving parts, as it burns completely. The oil needs to be changed less often. It does not liquefy and retains its properties longer. Cylinders and pistons wear less, which means engine life increases.

Recommended reading:

  • Painting and marking of gas cylinders
  • How much propane and butane mixture is consumed during welding?

Brief characteristics of alkanes

The simplest organic compounds include acyclic saturated or saturated hydrocarbons (alkanes). They are distinguished by the following structural features:

  • unbranched (straight) or branched molecules that do not contain cyclic formations;
  • All chemical bonds in a molecule are single.

The general formula looks like . The carbon chain in alkane molecules is characterized by complete saturation with hydrogen atoms, as a result of which these compounds exhibit weak chemical activity. They undergo substitution, oxidation, decomposition and isomerization reactions.

The substitution mechanism in alkanes is radical in nature, since the cleavage of the weakly polar CH bond proceeds with the formation of a pair of free radicals - neutral particles with one unpaired electron each. The hydrogen atom may be replaced by a halogen, a nitro group or a sulfo group.

Notes[ | ]

  1. Oleksiy Zivenko.
    LPG ACCOUNTING SPECIFICITY DURING ITS STORAGE AND TRANSPORTATION (English) // Measuring Equipment and Metrology. — 2022. — Vol. 80, iss. 3. - P. 21–27. — ISSN 2617-846X 0368-6418, 2617-846X. - doi:10.23939/istcmtm2019.03.021.
  2. https://www.firesprinkler.ru/dmdocuments/PZ_SP_S.pdf “Warehouses of liquefied hydrocarbon gases. Fire safety requirements"
  3. https://propane-butane.ru Horizontal tanks
  4. https://gazovik-ongk.ru/ Archived copy dated June 24, 2015 on the Wayback Machine Tanks and process equipment
  5. Zhang, Chunhua; Bian, Yaozhang; Si, Lizeng; Liao, Junzhi; Odbileg, N (2005). "A study on an electronically controlled liquid petroleum gas-diesel dual-fuel automobile." Proceedings of the Institution of Mechanical Engineers, Part D: Journal of Automobile Engineering 219 (2): 207. doi:10.1243/095440705X6470.
  6. Qi, D; Bian, Y; Ma, Z; Zhang, C; Liu, S (2007). "Combustion and exhaust emission characteristics of a compression ignition engine using liquefied petroleum gas-fuel-oil blended fuel." Energy Conversion and Management 48 (2): 500.

Methane chlorination

When exposed to sunlight, chlorine radicals replace all the hydrogen atoms in methane. To completely replace hydrogen, the proportion of chlorine in the mixture must be sufficient. Thus, four derivatives can be obtained from methane:

CH3Cl – chloromethane.

CH2Cl2 – dichloromethane.

CHCl3 – trichloromethane (chloroform).

CCl4 – carbon tetrachloride.

Partial oxidation

In industry, mixtures that are formed during the partial oxidation of methane are used to produce synthetic alkanes. From methane, with incomplete oxidation with air, methyl alcohol (CH3OH), formaldehyde (HCHO), and formic acid (HCOOH) can be obtained. And when butane is oxidized in industry, acetic acid is produced:

2С4Н10 + 5О2 → 4СН3СООН + 2Н2О

In order for alkanes to be partially oxidized, catalysts (Co2+, Mn2+, etc.) are used at relatively low air temperatures.

Substitution mechanism using the example of methane halogenation

Methane is considered the simplest alkane, so its halogenation reactions are easy to remember, and on this basis, carry out radical substitution of other alkanes. The halogen is usually chlorine. It has medium responsiveness. Alkanes do not react with iodine, since it is a weak halogen. The interaction with fluorine is explosive because fluorine atoms are very active. Although, during the substitution reaction of alkanes with chlorine, an explosion can also occur.

The origin of the chain. Under the influence of sunlight, ultraviolet radiation or heating, the chlorine molecule Cl2 breaks down into two free radicals. Each has one unpaired electron in its outer shell.

Cl2 → 2Cl

Development or growth of the chain. By interacting with methane molecules, free radicals form new ones and continue the chain of transformations.

CH4 + Cl → CH3 + HCl

CH3 + Cl2 → CH3Cl + Cl

The reaction continues until all free radicals disappear.

Chain termination is the final stage of radical substitution of alkanes. Radicals combine with each other and form new molecules.

CH3 + Cl → CH3Cl

CH3 + CH3 → CH3 – CH3

Mechanism of radical displacement reaction

The reaction mechanism has three stages:

  1. Initiation. Through external factors (heating, irradiation, chemical and electrical catalysts), the bond in the molecule of the substance is destroyed, forming free radicals.
  2. Development of the chain or its growth. Free elements interact with molecules, resulting in the formation of new substances and radicals.
  3. Circuit break. In the third stage, the radicals combine with each other. Their recombination occurs (the union of unpaired electrons that belong to different particles), due to which new independent molecules appear. There are no free radicals left and the reaction chain is considered complete.

Transport[ | ]

From manufacturing plants to consumers, liquefied hydrocarbon gases are delivered in pressure vessels or in isothermal (i.e., maintaining the same temperature) containers, as well as through pipelines. Delivery is a complex organizational, economic and technological process, including transportation of liquefied gases over long distances, processing of gases at railway and sea terminals, at cluster bases and gas filling stations, transporting them over short distances for direct delivery of gas to consumers.

Rail transport[ | ]

To transport liquefied hydrocarbon gases along the railway network, specially designed railway tank cars are used.
The tank is a welded cylindrical tank with elliptical bottoms, located on railway bogies. The tank is secured to the frame with coupling bolts. Technical characteristics of special tank cars for transportation of liquefied hydrocarbon gases

Model15-120015-1200-0215-122815-120915-1229
Load capacity, t3140,856,15153,5
Tare weight, t36 ± 3 %37,6 ± 3 %36,4…37,9 ± 3 %36,7 ± 3 %40
Body (boiler) volume, m³ (full)55,773,911083,8396,68
Wheelset load on rails, kN170194,8200217,78230,3
per linear meter, kN/m56,664,87072,576,6
Design speed, km/h120120120120120
Dimensions according to GOST 9238-8302-BM1-T1-T1-T1-T
Length, m
along the axes of automatic couplers12,0212,0215,2812,0215,28
along the frame end beams10,810,814,0610,814,06
Maximum width, m3,0563,0563,2823,198
Trolley model18-10018-10018-10018-10018-100
Boiler internal diameter, mm2600300032003000
Boiler pressure, MPa
redundant2,02,01,651,8
generated during hydraulic testing3,03,02,52,5
Main materialSteel 09G2S - 13 GOST 5520-79
Track width, mm1520 (1435)152015201520
Service life, years4040404040

Road transport[ | ]

In Russia, liquefied hydrocarbon gases are transported over relatively short distances (up to 300 km) in tank trucks.
An automobile tank is a horizontal cylindrical vessel with a hatch with instruments welded into the rear bottom. According to their design and purpose, tank trucks are divided into transport and dispensing. Transport tanks are used to transport relatively large quantities of liquefied gas from supplying plants to cluster bases and gas filling stations, from design bureaus and gas filling stations to large consumers and group installations with gas discharge into tanks. Dispensing tank trucks are designed to deliver liquefied petroleum gas to the consumer with filling into cylinders and are equipped with a full set of equipment (pump, dispensing frame) for filling. If necessary, dispensing tank trucks can be used as transport tanks. The outer surface of all tank trucks is painted with aluminum paint. On both sides of the protective casing of the tank along its entire length, distinctive red stripes 200 mm wide are applied along its entire length. Above the distinctive stripes and around the circumference of the flange, the inscriptions “Propane” (or other liquefied gas) and “Flammable” are written in black. The following stamps are stamped on the metal plate attached to the tanker: manufacturer; tank number according to the factory list, year of manufacture and date of inspection, total mass of the tank in tons, tank capacity in m³, operating and test pressure in MPa; factory quality control mark. Technical characteristics of tank semi-trailers

IndexTank semi-trailer brand
PPCT-12PPCT-15PPCT-20PPCT-31PPCT-45
Pressure, MPa, no more
Working1,61,61,61,61,6
Estimated1,81,81,81,81,8
Trial2,32,32,32,32,3
Geometric vessel capacity, m³12,4514,5 ± 0,119,72 ± 0,131,2 ± 0,145,75
Useful capacity of the tank, m³ (at a filling factor of 0.85)10,5812,3216,76 ± 0,126,5 ± 0,138,89
Mass of transported gas, kg, no more60807076962015 23721 000
Trolley typeTPK-16, SAT-109TPK-16-0001100TPA-301
Full weight of the semi-trailer, kg, no more13 08013 60019 780, 20 16026 76235 000
Distribution of the total weight of the tank semi-trailer along the axles, kg, no more
To the fifth wheel588064407980, 810011 02711 000
On the wheel axle720072001573524000
On the front axle, kg, no more5910, 6030
On the rear axle, kg, no more5910, 6030
Wheel track, mm18501850185018501850
Number of axles/wheels of a tank semi-trailer1/41/42/82/83/6
Base, mm476553005365+1320, 5365+13705490+13204330+1320+1320
Pump capacity, l/min.90up to 90
Overall dimensions, mm, no more
Length8350789010 42010 43511 500
Width25002500243024302490
Height31503190319035353650
Electric motor power, kW2225
Pump motor supply voltage, V380380380380
Pump capacity, l/min.909090220

Road transport is also used to transport liquefied hydrocarbon gases in cylinders.
The cylinders have two types - sizes 50 and 27 liters. Technical characteristics of "Cage" type cylinder carriers

Brand of cylinder tankATB-1-51PMLI
Load capacity, t.2,55,2
Vehicle baseGAZ-51GAZ-53MAZ-504
Number of cylinders:
capacity 50 l32112
capacity 27 l132
Mass of gas in cylinders, t0,71,453

Transportation of liquefied hydrocarbon gases by tankers[ | ]

In 2006, there were 934 gas tankers in the world with a total capacity of 8,650 thousand m³.

A modern gas tanker is a huge vessel, comparable in size to an oil supertanker. On average, the cargo capacity of gas carriers, depending on the type of gas and the method of its liquefaction, is 100-200 thousand m³.

The speed of gas carriers varies from 9 to 20 knots (16.7-37 km per hour). Diesels are most often used as engines. The average cost of a gas carrier is $160-180 million, which is approximately five times higher than the cost of building an oil tanker of similar displacement.

According to the architectural and structural type, gas carriers are vessels with a stern arrangement of the engine room and superstructure, a double bottom (lately only gas carriers with double sides are built) and ballast tanks.

For the transportation of liquefied hydrocarbon gases, loose cargo tanks with a design pressure on average of no more than 2 MPa are used. They are placed both on the deck and in the holds on special foundations. The material used for tanks is usually carbon steel.

There are three types of vessels for transporting liquefied petroleum gases.

  • Tankers with pressurized tanks.
    The tanks of these tankers are designed for the maximum vapor pressure of the product at +45 °C, which is about 18 kgf/cm². The weight of the cargo tanks of such tankers significantly exceeds the weight of similar devices for other methods of transporting liquefied gases, which accordingly increases the overall dimensions and cost of the vessel. Tankers with a tank capacity of up to 4000 m³ and a loading capacity of 30-200 t/h are used with relatively small cargo flows and the absence of special equipment at coastal bases and tankers
  • Tankers with thermally insulated tanks under reduced pressure
    are semi-isothermal (semi-cooled). Liquefied gas is transported under intermediate cooling (from −5 to +5 °C) and reduced pressure (3–6 kgf/cm²). Such tankers are characterized by their versatility from coastal liquefied gas bases at various temperature parameters. Due to the reduction in the weight of cargo tanks, the size of the tanker is reduced and the efficiency of using tank volume increases. Tank capacity is 2000-15000 m³. Loading and unloading capacity is 100–420 t/h. These tankers are used for significant cargo turnover and with the availability of appropriate equipment at coastal bases and tankers.
  • Tankers with thermally insulated tanks under pressure close to atmospheric pressure
    are isothermal (low temperature). In isothermal tankers, liquefied gases are transported at near-atmospheric pressure and low negative temperatures (−40 °C for propane). This type of tankers is the most advanced; they allow increasing unloading and loading productivity and, accordingly, the throughput of coastal bases and fleet turnover. The tank capacity is more than 10,000 m³. Loading capacity 500-1000 t/h or more. They are characterized by large sizes and are used for significant cargo turnover.

World fleet for the transportation of liquefied hydrocarbon gases

No.Capacity, m³High pressureSemi-chilledLow temperatureTOTAL
1up to 10002626
21000 — 10 00040524019664
310 000 — 20 0002561472
420 000 — 60 00057277
5over 60,0009595
6Total433301200934
7Minimum temperature, °C0−50−50…−104
8Maximum pressure, atm.184-60,3

Characteristics of some liquefied petroleum gas tankers

TankerCapacity m³ (t)ReservoirsTechnological characteristicsEngine
NumberTypePressure, kgf/cm²TemperatureNumber of compressorsNumber of pumpsLoading speed, t/hTypePower, l. With. Speed, km/hFuel
"Kegums" (Russia)2080 (1125)4Spherical17,5Environment22200Two-stroke cylinder240024Gas oil
"Kraslava" (Russia)2080 (1125)4Spherical17,5Environment22200Two-stroke cylinder340024Diesel
"Rasmus Tolstrum" (Denmark)1042 (520)5Vertical (2) Spherical (3)17,5Environment2245Four-stroke eight-cylinder100019Gas oil
Medgaz (Greece)800 (400)14Vertical17,45EnvironmentTwo two-stroke each with 4 cylinders13Gas oil
"Too So Maru" (Japan)13 355Isothermal0,05According to pressureTurboelectric6000Liquefied gas, oil
Cap Martin (France)13 196 (6900)9Horizontal semi-isothermal5According to pressure3420Two-stroke five-cylinder465027Oil
"Froston" (Norway)4100 (2215)6Horizontal semi-isothermal5According to pressure34250Two-stroke six-cylinder345025Diesel
"Jule" (England)2456 (1325)6Horizontal semi-isothermal8According to pressure23100Four-stroke, ten-cylinder267026Diesel
"Esso Flame" (Finland)1050 (500)3Horizontal semi-isothermal5−1…+10 °C3285Diesel120024Diesel
Newton (Spain)2180 (1170)8Horizontal semi-isothermal7,5According to pressure32105Four-stroke, eight-cylinder150024Gas oil
Agipgaz Quorta (Italy)1850 (100)18Vertical17,5Environment2240Four-stroke, eight-cylinder21Gas oil
"Shiroyama Maru" (Japan)461004Isothermal0,05According to pressureTwo-stroke, eight-cylinder120026Liquefied gas, oil
"Jules Verne" (France)25 500 (12060)7Cylindrical, isothermal0,01−162 °C1433002 steam turbines1150029Oil
"Thetan Princesses" (England)27400(12070)9Rectangular, isothermal0,01−162 °C99002 steam turbines1150029Oil

Oxidation reactions

Free radicals again participate in the oxidation reactions of alkanes. In this case, the O2 radical attaches to the alkane molecule, and a complete or incomplete oxidation reaction occurs. Complete oxidation is called combustion:

CH4 + 2O2 → CO2 + 2H2O

The combustion reaction of alkanes by the radical substitution mechanism is widely used in industry as fuel for thermal power plants and internal combustion engines. Only branched alkanes can be placed in such machine engines. Simple linear alkanes explode in internal combustion engines. From the non-volatile sediment formed as a result of radical replacement, lubricants, asphalt, paraffin, etc. are produced.

Properties[ | ]

Brand options[ | ]

Indicator nameTechnical propaneAutomotive propanePropane-butane for automobilesPropane-butane technicalTechnical butane
1. Mass fraction of components
Sum of methane, ethane and ethyleneNot standardized
Sum of propane and propylenenot less than 75% wt.Not standardized
including propanenot standardizednot less than 85±10% wt.not less than 50±10% wt.not standardizednot standardized
Sum of butanes and butylenesnot standardizednot standardizednot standardizedno more than 60% of the mass.not less than 60% wt.
Total unsaturated hydrocarbonsnot standardizedno more than 6% wt.no more than 6% wt.not standardizednot standardized
2. Liquid residue fraction at 20 °Cno more than 0.7% vol.no more than 0.7% vol.no more than 1.6% vol.no more than 1.6% vol.no more than 1.8% vol.
3. Saturated steam pressurenot less than 0.16 MPa
(at −20 °C)
not less than 0.07 MPa
(at −30 °C)
no more than 1.6 MPa
(at +45 °C)
not standardizednot standardized
4. Mass fraction of hydrogen sulfide and mercaptan sulfurno more than 0.013% wt.no more than 0.01% wt.no more than 0.01% wt.no more than 0.013% wt.no more than 0.013% wt.
including hydrogen sulfideno more than 0.003% wt.
5. Free water contentabsence
6. Odor intensity, pointsat least 3

Liquefied hydrocarbon gases are fire and explosive, low toxic, have a specific characteristic odor of hydrocarbons, and according to the degree of impact on the body they are classified as substances of the 4th hazard class. The maximum permissible concentration of LPG in the air of the working area (in terms of carbon) of saturated hydrocarbons (propane, butane) is 300 mg/m³, unsaturated hydrocarbons (propylene, butylene) is 100 mg/m³.

LPG forms explosive mixtures with air at a concentration of propane vapor from 2.3 to 9.5%, normal butane from 1.8 to 9.1% (by volume), at a pressure of 0.1 MPa and a temperature of 15 - 20 °C. The auto-ignition temperature of propane in air is 470 °C, normal butane is 405 °C.

Physical characteristics[ | ]

IndexMethaneEthaneEthylenePropanePropylenen-ButaneIsobutanen-ButyleneIsobutylenen-Pentane
Chemical formulaCH4С2Н6С2Н4С3Н8C3H6С4Н10С4Н10С4Н8С4Н8S5H12
Molecular weight, kg/kmol16,04330,06828,05444,09742,08158,12458,12456,10856,10472,146
Molecular volume, m³/kmol22,3822,17422,26321,99721,97421,5021,74322,44222,44220,87
Gas phase density, kg/m³, at 0 °C0,71681,3561,2602,00371,91492,70232,6852,552,50223,457
Gas phase density, kg/m³, at 20°0,6681,2631,1741,8721,7842,5192,4862,3292,3293,221
Liquid phase density, kg/m³, at 0°416546566528609601582646646645,5
Boiling point, at 101.3 kPa−161−88,6−104−42,1−47,7−0,50−11,73−6,903,7236,07
Lower calorific value, MJ/m³35,7663,6559,5391,1486,49118,53118,23113,83113,83146,18
Higher calorific value, MJ/m³40,1669,6963,0499,1791,95128,5128,28121,4121,4158
Ignition temperature, °C545-800530-694510-543504-588455-550430-569490-570440-500400-440284-510
Octane number11012510012511591,2099,3580,3087,5064,45
Theoretically required amount of air
for combustion, m³/m³
9,5216,6614,2823,822,4230,9430,9428,5628,5638,08

Critical parameters of gases[ | ]

Gases can be converted into a liquid state by compression if the temperature does not exceed a certain value characteristic of each homogeneous gas. The temperature above which a given gas cannot be liquefied by any increase in pressure is called the critical temperature. The pressure required to liquefy the gas at this critical temperature is called the critical pressure.

IndexMethaneEthaneEthylenePropanePropylenen-ButaneIsobutanen-ButyleneIsobutylenen-Pentane
Critical temperature, °C−82,532,39,996,8491,94152,01134,98144,4155196,6
Critical pressure, MPa4,584,825,0334,214,543,7473,63,9454,103,331

Saturated vapor pressure[ | ]

The saturated vapor pressure of liquefied gases is the pressure at which the liquid is in equilibrium with its gas phase. In this state of the two-phase system, neither vapor condensation nor liquid evaporation occurs. Each component of LPG at a certain temperature corresponds to a certain saturated vapor pressure, which increases with increasing temperature. The pressure in the table is indicated in MPa.

Temperature, °CEthanePropaneIsobutanen-Butanen-PentaneEthylenePropylenen-ButyleneIsobutylene
−500,5530,071,0470,1000,0700,073
−450,6550,0881,2280,1230,0860,089
−400,7710,1091,4320,1500,1050,108
−350,9020,1341,6600,1810,1270,130
−301,0500,1641,9120,2160,1520,155
−251,2150,1972,1920,2590,1820,184
−201,4000,2362,4980,3080,2150,217
−151,6040,2850,0880,0562,8330,3620,2520,255
−101,8310,3380,1070,0683,1990,4230,2950,297
−52,0810,3990,1280,0843,5960,4970,3430,345
02,3550,4660,1530,1020,0244,0250,5750,3960,399
+52,5550,5430,1820,1230,0304,4880,6650,4560,458
+102,9820,6290,2150,1460,0375,0000,7640,5220,524
+153,3360,7250,2520,1740,0460,8740,5940,598
+203,7210,8330,2940,2050,0581,0200,6880,613
+254,1370,9510,3410,2400,0671,1320,6940,678
+304,4601,0800,3940,2800,0811,2800,8560,864
+354,8891,2260,4520,3240,0961,4440,9600,969
+401,3820,5130,3740,1141,6231,0721,084
+451,5520,5900,4290,1341,8171,1931,206
+501,7400,6700,4900,1572,0281,3231,344
+551,9430,7590,5570,1832,2571,4641,489
+602,1620,8530,6310,2122,5051,5881,645

Dependence of density on temperature[ | ]

The density of the liquid and gas phases of LPG depends significantly on temperature. Thus, the density of the liquid phase decreases with increasing temperature, and vice versa, the density of the vapor phase increases.

It should be noted that when storage conditions change (temperature, pressure), the component composition of the LPG phases also changes, which is important to take into account for some applications [1].

Data on the density values ​​of LPG components at various temperatures are given in Table.

Temperature, °CPropaneIsobutanen-Butane
Specific volumeDensitySpecific volumeDensitySpecific volumeDensity
Liquid, l/kgSteam, m³/kgLiquid, kg/lSteam, kg/m³Liquid, l/kgSteam, m³/kgLiquid, kg/lSteam, kg/m³Liquid, l/kgSteam, m³/kgLiquid, kg/lSteam, kg/m³
−601,6500,9010,6061,11
−551,6720,7350,5981,36
−501,6860,5520,5931,810
−451,7040,4830,5872,07
−401,7210,3830,5812,610
−351,7390,3080,5753,250
−301,7700,2580,5653,8701,6160,6710,6191,490
−251,7890,2160,5594,6201,6390,6060,6101,650
−201,8080,18250,5535,4801,6500,5100,6061,960
−151,8250,1560,5486,4001,6670,4000,6002,5001,6260,6240,6151,602
−101,8450,1320,5427,5701,6840,3290,5943,0401,6350,5140,6121,947
−51,8690,1100,5359,0501,7010,2790,5883,5901,6530,4760,6052,100
01,8940,0970,52810,3401,7180,2320,5824,3101,6640,3550,6012,820
51.9190.0840.52111.9001.7420.1970.5745.0701.6780.2990.5963.350
101,9460,0740,51413,6001,7560,1690,56945,9201,6940,2540,59023,94
151,9720,0640,50715,511,7700,1440,5656,9501,7150,2150,5834,650
202,0040,0560,49917,7401,7940,1260,55737,9401,7270,1860,57095,390
252,0410,04960,49020,1501,8150,1090,55119,2101,7450,1620,57326,180
302,0700,04390,48322,8001,8360,0870,544811,501,7630,1390,56737,190
352,1100,03950,47425,301,8520,0770,54013,001,7790,1220,5628,170
402,1550,0350,46428,601,8730,0680,53414,7001,8010,1070,55529,334
452,2170,0290,45134,501,8980,0600,52716,8001,8210,09460,54910,571
502,2420,0270,44636,8001,92980,0530,518218,9401,8430,08260,542612,10
552.2880.02490.43740.2201.9490.0490.51320.5601.8660.08080.53612.380
602,3040,02240,43444,601,9800,0410,50524,2001,8800,06430,53215,400

Content

  • 1 Classification
  • 2 Properties 2.1 Trademark parameters
  • 2.2 Physical characteristics
  • 2.3 Critical parameters of gases
  • 2.4 Vapor pressure
  • 2.5 Dependence of density on temperature
  • 3 Transport
      3.1 Rail transport
  • 3.2 Road transport
  • 3.3 Transportation of liquefied hydrocarbon gases by tankers
  • 4 Storage
  • 5 Application
      5.1 Fuel
  • 5.2 Products for organic synthesis
  • 6 See also
  • 7 Notes
  • 8 Literature
  • 9 Links
  • Rating
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